Sadly, there is no publicly available codec for the Photoshop PSD format but the newly released Microsoft Expression Blend 3 design tool includes such a codec so installing Blend 3 automatically installs the PSD codec. For those who don’t have a need for Blend and don’t want to install it, here is a little hacking guide to get the codec (a 256KB dll) and use it separately:
Get the codec and its dependencies:
Download the DLL below in the article attachments and save it.
Extract it to the %windir%\system32 directory, or any location that you prefer.
Register the codec from an administrator’s command prompt by running the following command: "regsvr32 %windir%\system32\PSDCodec.dll” (replace '%windir%\system32' with the location that you saved or copied the file to.)
Portions excerpted from http://www.ghacks.net/2009/07/29/view-photoshop-psd-thumbnails-in-vista-and-windows-7-explorer/.